Electrochemical Wastewater Treatment, Principles, Efficiency, and Applications: A Review

Main Article Content

Slwan Dhafer Basheer
https://orcid.org/0009-0001-2275-8440
Seroor Atallah Khaleefa Ali
Tasnim Fahem Chyad

Abstract

Wastewater pollution is an important and worrying issue because it can destroy aquatic life and deplete natural water resources. Electrochemical wastewater treatment has provided a new and promising opportunity, supported by an in-depth understanding of its working mechanisms and treatment efficiency. This article discusses the key theories, operational strategies, and influencing factors of electrochemical treatment, including electrode materials, pH levels, and process conditions. In addition, separation, conversion, and hybrid electrochemical processes are presented with particular attention to the generation of reactive species and the recovery of valuable byproducts such as metal ions. These processes demonstrate dual functionality both in contaminant removal and resource recovery highlighting the robustness and flexibility of electrochemical systems across a wide range of pollutants. Moreover, the article reviews various reactor designs and discusses the scalability of these systems for practical applications. This comprehensive overview emphasizes the potential of electrochemical technologies as efficient, adaptable, and environmentally friendly solutions for modern wastewater treatment challenges.

Article Details

How to Cite
[1]
slwan dhafer, Seroor Atalah, and Tasnim, “Electrochemical Wastewater Treatment, Principles, Efficiency, and Applications: A Review”, Rafidain J. Eng. Sci., vol. 3, no. 2, pp. 210–223, Jul. 2025, doi: 10.61268/tqq22q12.
Section
Review Articles

How to Cite

[1]
slwan dhafer, Seroor Atalah, and Tasnim, “Electrochemical Wastewater Treatment, Principles, Efficiency, and Applications: A Review”, Rafidain J. Eng. Sci., vol. 3, no. 2, pp. 210–223, Jul. 2025, doi: 10.61268/tqq22q12.

References

M. A. Hussein, S. Sadiq, and Z. Abudi, “Assessment of Sulfate and Chloride Concentrations in Groundwater and Their Impact on Public Health and the Environment in Iraq: A review,” Al-Rafidain J. Eng. Sci., pp. 69–79, 2025.

O. D. Ogundele, D. A. Oyegoke, and T. E. Anaun, “Exploring the potential and challenges of electro-chemical processes for sustainable waste water remediation and treatment,” Acadlore Trans Geosci, vol. 2, no. 2, pp. 80–93, 2023.

J. Radjenovic and D. L. Sedlak, “Challenges and Opportunities for Electrochemical Processes as Next-Generation Technologies for the Treatment of Contaminated Water,” Environ. Sci. Technol., vol. 49, no. 19, pp. 11292–11302, Oct. 2015, doi: 10.1021/acs.est.5b02414.

G. Z. Kyzas and K. A. Matis, “Electroflotation process: A review,” J. Mol. Liq., vol. 220, pp. 657–664, 2016.

E. Yakamercan, P. Bhatt, A. Aygun, A. W. Adesope, and H. Simsek, “Comprehensive understanding of electrochemical treatment systems combined with biological processes for wastewater remediation,” Environ. Pollut., vol. 330, p. 121680, Aug. 2023, doi: 10.1016/j.envpol.2023.121680.

S. Y. Nee Kew and S. Y. Lau, “Review of electrochemical reactors for the efficient removal of heavy metals from wastewater,” J. Ind. Eng. Chem., May 2025, doi: 10.1016/j.jiec.2025.04.062.

G. Chen, “Electrochemical technologies in wastewater treatment,” Sep. Purif. Technol., vol. 38, no. 1, pp. 11–41, 2004.

A. S. Bairagi, “Electrochemical Abatement of Diclofenac with Various Electrode Systems for Water Treatment Applications,” Sustain. Chem. Environ., p. 100237, 2025.

N. O. Etafo, D. G. Adekanmi, O. S. Awobifa, J. R. P. Torres, L. A. I. Herrera, and O. A. Awobifa, “Clean and green: the multifaceted solution of the electrocoagulation technology in emerging contaminants in wastewater,” Discov. Civ. Eng., vol. 2, no. 1, Jun. 2025, doi: 10.1007/s44290-025-00261-5.

Y. Feng, L. Yang, J. Liu, and B. E. Logan, “Electrochemical technologies for wastewater treatment and resource reclamation,” Environ. Sci. Water Res. Technol., vol. 2, no. 5, pp. 800–831, 2016.

F. Long, D. Ghani, R. Huang, and C. Zhao, “Versatile electrode materials applied in the electrochemical advanced oxidation processes for wastewater treatment: A systematic review,” Sep. Purif. Technol., vol. 354, p. 128725, 2025.

A. Mirshafiee, M. Nourollahi, and A. Shahriary, “Application of electro oxidation process for treating wastewater from petrochemical with mixed metal oxide electrode,” Sci. Rep., vol. 14, no. 1, p. 1760, 2024.

J. M. Costa, “Considerations on electrochemical technologies for water purification and wastewater treatment,” International journal of environmental research and public health, vol. 20, no. 12. MDPI, p. 6140, 2023. Accessed: Jul. 14, 2025. [Online]. Available: https://www.mdpi.com/1660-4601/20/12/6140

K. H. H. Aziz, F. S. Mustafa, M. A. Karim, and S. Hama, “Pharmaceutical pollution in the aquatic environment: advanced oxidation processes as efficient treatment approaches: a review,” Mater. Adv., 2025, Accessed: Jul. 14, 2025. [Online]. Available: https://pubs.rsc.org/en/content/articlehtml/2025/ma/d4ma01122h

C. Barrera-Díaz, P. Canizares, F. J. Fernández, R. Natividad, and M. A. Rodrigo, “Electrochemical advanced oxidation processes: an overview of the current applications to actual industrial effluents,” J. Mex. Chem. Soc., vol. 58, no. 3, pp. 256–275, 2014.

J. T. Jasper, Y. Yang, and M. R. Hoffmann, “Toxic Byproduct Formation during Electrochemical Treatment of Latrine Wastewater,” Environ. Sci. Technol., vol. 51, no. 12, pp. 7111–7119, Jun. 2017, doi: 10.1021/acs.est.7b01002.

M. Rodríguez-Peña, R. Natividad, C. E. Barrera-Díaz, P. Balderas Hernández, C. I. Alanis Ramírez, and G. Roa-Morales, “Current perspective of advanced electrochemical oxidation processes in wastewater treatment and life cycle analysis,” Int. J. Electrochem. Sci., vol. 19, no. 7, p. 100589, Jul. 2024, doi: 10.1016/j.ijoes.2024.100589.

J. Lee, S. Kim, C. Kim, and J. Yoon, “Hybrid capacitive deionization to enhance the desalination performance of capacitive techniques,” Energy Environ. Sci., vol. 7, no. 11, pp. 3683–3689, 2014.

L. Mendia, “Electrochemical processes for wastewater treatment,” Water Sci. Technol., vol. 14, no. 1–2, pp. 331–344, 1982.

P. Subramani et al., “Water recycling public toilets based on onsite electrochemical wastewater treatment,” Environ. Sci. Water Res. Technol., vol. 10, no. 1, pp. 157–167, 2024.

“Continuous Flow‐By Electrochemical Reactor Design for Direct Lithium Extraction from Brines - Roggerone - 2024 - ChemElectroChem - Wiley Online Library.” Accessed: Jul. 15, 2025. [Online]. Available: https://chemistry-europe.onlinelibrary.wiley.com/doi/full/10.1002/celc.202400160

F. Y. AlJaberi and Z. A. Hawaas, “Electrocoagulation removal of Pb, Cd, and Cu ions from wastewater using a new configuration of electrodes,” MethodsX, vol. 10, p. 101951, 2023.

Y. Yu, Y. Zhong, W. Sun, J. Xie, M. Wang, and Z. Guo, “A novel electrocoagulation process with centrifugal electrodes for wastewater treatment: Electrochemical behavior of anode and kinetics of heavy metal removal,” Chemosphere, vol. 310, p. 136862, 2023.

Z. A. Kadhim and A. H. Abbar, “Cadmium Removal Using Bio-Electrochemical Reactor with Packed Bed Rotating Cylindrical Cathode: A Kinetics Study,” Iraqi J. Chem. Pet. Eng., vol. 23, no. 3, pp. 51–58, 2022.

A. Al Ali, M. Ouda, V. Naddeo, S. Puig, and S. W. Hasan, “Integrated electrochemical-adsorption process for the removal of trace heavy metals from wastewater,” Case Stud. Chem. Environ. Eng., vol. 4, p. 100147, 2021.

M. Hu, Z. Sun, J. Hu, H. Lei, and W. Jin, “Simultaneous Phenol Detoxification and Dilute Metal Recovery in Cyclone Electrochemical Reactor,” Ind. Eng. Chem. Res., vol. 58, no. 28, pp. 12642–12649, Jul. 2019, doi: 10.1021/acs.iecr.9b02453.

J. Lee et al., “Electrochemical Methods for Nutrient Removal in Wastewater: A Review of Advanced Electrode Materials, Processes, and Applications. Sustainability 2024, 16, 9764.” 2024. Accessed: Jul. 14, 2025. [Online]. Available: https://www.academia.edu/download/119433707/sustainability_16_09764.pdf

M. A. Alkhadra et al., “Electrochemical Methods for Water Purification, Ion Separations, and Energy Conversion,” Chem. Rev., vol. 122, no. 16, pp. 13547–13635, Aug. 2022, doi: 10.1021/acs.chemrev.1c00396.