Comparative Removal of Crystal Violet Dye Using Peanut Hull Powder and Its Modified Forms: Adsorption Mechanisms, Isotherms, and Kinetics
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Abstract
In this work, the removal of cationic dye; Crystal Violet (CV) by (Peanut Hull Powder (PHP), activation of Peanut Hull Powder (PHPAC) with HCl, and activated carbon derived from PHP) from aqueous solution in batch experiments. The adsorbents were characterized using BET for analysis of the specific surface area. The finding showed that the adsorption capacities of PHP, PHPAC, and PHPAC were 95.5 %, 96.8 %, and 98.7 % respectively. Under ideal circumstances, the isotherms of adsorption using the Langmuir, Freundlich, Sips, and Temkin isotherm models were used to validate the experimental data. The maximum adsorption capacity (qmax), as determined by isotherm investigations, was 13.25815 mg/g. The Freundlich Model is the better-fitting model with the highest R2 value in the PHP experiments. According to the kinetic analysis, the pseudo-second-order better describes the adsorption behavior. The study found that adjusting factors like pH, temperature, contact duration, adsorbent dose, adsorbent particle size, and the stirring rate significantly improved adsorption efficiency. The results show much higher dye removal rates under these conditions at the optimum values; 6, 25°C, 60 min, 1.5 g, 150 µm, and 120 rpm for the above-mentioned conditions respectively, and offer a thorough investigation of adsorption kinetics and isotherms. This research provides new insights into the adsorption mechanism and suggests potential applications for industrial wastewater treatment, promoting more sustainable and cost-effective solutions.
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R. Foroutan, S. J. Peighambardoust, S. H. Peighambardoust, M. Pateiro, and J. M. Lorenzo, "Adsorption of crystal violet dye using activated carbon of lemon wood and activated carbon/Fe3O4 magnetic nanocomposite from aqueous solutions: a kinetic, equilibrium and thermodynamic study," Molecules, vol. 26, p. 2241, 2021. doi: 10.1007/s13738-022-02500-3.
A. Azanaw, B. Birlie, B. Teshome, and M. Jemberie, "Textile effluent treatment methods and eco-friendly resolution of textile wastewater," Case Studies in Chemical and Environmental Engineering, vol. 6, p. 100230, 2022. doi: 10.1016/j.cscee.2022.100230.
S. Benkhaya, S. M'rabet, and A. El Harfi, "A review on classifications, recent synthesis and applications of textile dyes," Inorganic Chemistry Communications, vol. 115, p. 107891, 2020. doi: 10.1016/j.inoche.2020.107891.
S. S. Affat, "Classifications, advantages, disadvantages, toxicity effects of natural and synthetic dyes: a review," University of Thi-Qar Journal of Science, vol. 8, pp. 130-135, 2021.
V. Chandanshive, S. Kadam, N. Rane, B.-H. Jeon, J. Jadhav, and S. Govindwar, "In situ textile wastewater treatment in high rate transpiration system furrows planted with aquatic macrophytes and floating phytobeds," Chemosphere, vol. 252, p. 126513, 2020. doi: 10.1016/j.chemosphere.2020.126513.
N. P. Raval, P. U. Shah, and N. K. Shah, "Malachite green “a cationic dye” and its removal from aqueous solution by adsorption," Applied Water Science, vol. 7, pp. 3407-3445, 2017. doi: 10.1007/s13201-016-0512-2.
M. Sardar, M. Manna, M. Maharana, and S. Sen, "Remediation of dyes from industrial wastewater using low-cost adsorbents," Green adsorbents to remove metals, dyes, and boron from polluted water, pp. 377-403, 2021. doi: 10.1007/978-3-030-47400-3_15.
A. Goksu and M. K. Tanaydin, "Adsorption of hazardous crystal violet dye by almond shells and determination of optimum process conditions by Taguchi method," Desalination and Water Treatment, vol. 88, pp. 189-199, 2017. doi: 10.5004/dwt.2017.21364.
I. Loulidi, M. Jabri, A. Amar, A. Kali, A. A. Alrashdi, C. Hadey, et al., "Comparative study on adsorption of crystal violet and Chromium (VI) by activated carbon derived from spent coffee grounds," Applied Sciences, vol. 13, p. 985, 2023. doi: 10.3390/app13020985
H. Wu, R. Chen, H. Du, J. Zhang, L. Shi, Y. Qin, et al., "Synthesis of activated carbon from peanut shell as dye adsorbents for wastewater treatment," Adsorption Science & Technology, vol. 37, pp. 34-48, 2019. doi: 10.1177/0263617418807856.
X. Pang, L. Sellaoui, D. Franco, G. L. Dotto, J. Georgin, A. Bajahzar, et al., "Adsorption of crystal violet on biomasses from pecan nutshell, para chestnut husk, araucaria bark and palm cactus: experimental study and theoretical modeling via monolayer and double layer statistical physics models," Chemical Engineering Journal, vol. 378, p. 122101, 2019. doi: 10.1016/j.cej.2019.122101.
S. Shojaei, S. Shojaei, S. S. Band, A. A. K. Farizhandi, M. Ghoroqi, and A. Mosavi, "Application of Taguchi method and response surface methodology into the removal of malachite green and auramine-O by NaX nanozeolites," Scientific reports, vol. 11, p. 16054, 2021. doi: 10.1038/s41598-021-95649-5.
M. Alshammari, M. F. Al Juboury, L. A. Naji, A. A. Faisal, H. Zhu, N. Al-Ansari, et al., "Synthesis of a novel composite sorbent coated with siderite nanoparticles and its application for the remediation of water contaminated with Congo red dye," International Journal of Environmental Research, vol. 14, pp. 177-191, 2020. doi: 10.1007/s41742-020-00245-6.
S. J. Mohammed, M. J. M-Ridha, K. M. Abed, and A. A. Elgharbawy, "Removal of levofloxacin and ciprofloxacin from aqueous solutions and an economic evaluation using the electrocoagulation process," International Journal of Environmental Analytical Chemistry, vol. 103, pp. 3801-3819, 2023. doi: 10.1080/03067319.2021.1913733.
M. S. Salman, H. S. Alhares, Q. A. Ali, M. J. M-Ridha, S. J. Mohammed, and K. M. Abed, "Cladophora algae modified with CuO nanoparticles for tetracycline removal from aqueous solutions," Water, Air, & Soil Pollution, vol. 233, p. 321, 2022. doi: 10.1007/s11270-022-05813-4.
A. L. Vega-Negron, L. Alamo-Nole, O. Perales-Perez, A. M. Gonzalez-Mederos, C. Jusino-Olivencia, and F. R. Roman-Velazquez, "Simultaneous adsorption of cationic and anionic dyes by chitosan/cellulose beads for wastewaters treatment," International Journal of Environmental Research, vol. 12, pp. 59-65, 2018. doi: 10.1007/s41742-018-0066-2.
K. Al-Zawahreh, M. T. Barral, Y. Al-Degs, and R. Paradelo, "Competitive removal of textile dyes from solution by pine bark-compost in batch and fixed bed column experiments," Environmental Technology & Innovation, vol. 27, p. 102421, 2022. doi: 10.1016/j.eti.2022.102421.
X. You, R. Wang, Y. Zhu, W. Sui, and D. Cheng, "Comparison of adsorption properties of a cellulose-rich modified rice husk for the removal of methylene blue and aluminum (III) from their aqueous solution," Industrial Crops and Products, vol. 170, p. 113687, 2021. doi: 10.1016/j.indcrop.2021.113687.
S. Husien, R. M. El-taweel, A. I. Salim, I. S. Fahim, L. A. Said, and A. G. Radwan, "Review of activated carbon adsorbent material for textile dyes removal: Preparation, and modelling," Current Research in Green and Sustainable Chemistry, vol. 5, p. 100325, 2022. doi: 10.1016/j.crgsc.2022.100325.
S. J. Mohammeda, M. J. M-Ridhab, Q. A. Alic, K. M. Abedd, and S. Ahmadzadehf, "Reliable treatment approach for levofloxacin and ciprofloxacin removal from aqueous medium: process modelling, kinetic and isotherm studies," DESALINATION AND WATER TREATMENT, vol. 307, pp. 50-62, 2023. doi: 10.5004/dwt.2023.29776.
S. Mohammed and M. Mohammed-Ridha, "Optimization of levofloxacin removal from aqueous solution using electrocoagulation process by response surface methodology," Iraqi Journal of Agricultural Sciences, vol. 52, pp. 204-217, 2021.
W. Chen, H. Ma, and B. Xing, "Electrospinning of multifunctional cellulose acetate membrane and its adsorption properties for ionic dyes," International journal of biological macromolecules, vol. 158, pp. 1342-1351, 2020.
I. Ghosh, S. Kar, T. Chatterjee, N. Bar, and S. K. Das, "Adsorptive removal of Safranin-O dye from aqueous medium using coconut coir and its acid-treated forms: adsorption study, scale-up design, MPR and GA-ANN modeling," Sustainable Chemistry and Pharmacy, vol. 19, p. 100374, 2021. doi: 10.1016/j.scp.2021.100374.
M. S. Hossain, F. Omar, A. J. Asis, R. T. Bachmann, M. Z. I. Sarker, and M. O. Ab Kadir, "Effective treatment of palm oil mill effluent using FeSO4. 7H2O waste from titanium oxide industry: Coagulation adsorption isotherm and kinetics studies," Journal of Cleaner Production, vol. 219, pp. 86-98, 2019. doi: 10.1016/j.jclepro.2019.02.069.
M. Benjelloun, Y. Miyah, G. A. Evrendilek, F. Zerrouq, and S. Lairini, "Recent advances in adsorption kinetic models: their application to dye types," Arabian Journal of Chemistry, vol. 14, p. 103031, 2021. doi: 10.1016/j.arabjc.2021.103031.
N. Yasarawan, "Removal of crystal violet dye in aqueous solution by adsorption onto adsorbents derived from peanut shells," Burapha Science Journal, pp. 394-413, 2022. doi: 10.1007/s12649-012-9139-1.
F. Abbasi, M. T. Yaraki, A. Farrokhnia, and M. Bamdad, "Keratin nanoparticles obtained from human hair for removal of crystal violet from aqueous solution: Optimized by Taguchi method," International journal of biological macromolecules, vol. 143, pp. 492-500, 2020. doi: 10.1016/j.ijbiomac.2019.12.065.
S. Abbas, T. Javeed, S. Zafar, M. B. Taj, A. R. Ashraf, and M. I. Din, "Adsorption of crystal violet dye by using a low-cost adsorbent–peanut husk," Desalination and Water Treatment, vol. 233, pp. 387-398, 2021. doi: 10.5004/dwt.2021.27538.
G. K. Cheruiyot, W. C. Wanyonyi, J. J. Kiplimo, and E. N. Maina, "Adsorption of toxic crystal violet dye using coffee husks: Equilibrium, kinetics and thermodynamics study," Scientific African, vol. 5, p. e00116, 2019. doi: 10.1016/j.sciaf.2019.e00116.
K. M. Abed, B. M. Kurji, S. A. Rashid, and B. A. Abdulmajeed, "Kinetics and thermodynamics of peppermint oil extraction from peppermint leaves," Iraqi Journal of Chemical and Petroleum Engineering, vol. 20, pp. 1-6, 2019. doi: 10.31699/IJCPE.2019.4.1.
F. Brouers and T. J. Al-Musawi, "Brouers-Sotolongo fractal kinetics versus fractional derivative kinetics: a new strategy to analyze the pollutants sorption kinetics in porous materials," Journal of hazardous materials, vol. 350, pp. 162-168, 2018. doi: 10.1016/j.jhazmat.2018.02.015.
N. J. Okorocha, C. E. Omaliko, C. C. Osuagwu, M. Chijioke-Okere, and C. K. Enenebeaku, "Utilization of agro-waste in the elimination of dyes from aqueous solution: equilibrium, kinetic and thermodynamic studies," International Letters of Chemistry, Physics and Astronomy, vol. 86, pp. 11-23, 2021. doi: 10.18052/www.scipress.com/ILCPA.86.11.
S. Sultana, K. Islam, M. A. Hasan, H. J. Khan, M. A. R. Khan, A. Deb, et al., "Adsorption of crystal violet dye by coconut husk powder: isotherm, kinetics and thermodynamics perspectives," Environmental Nanotechnology, Monitoring & Management, vol. 17, p. 100651, 2022. doi: 10.1016/j.enmm.2022.100651.
S. Khadama, T. Javeda, and M. I. Jilanib, "Adsorptive exclusion of crystal violet dye from wastewater using eggshells: kinetic and thermodynamic study," DESALINATION AND WATER TREATMENT, vol. 268, pp. 99-112, 2022. doi: 10.1007/s12649-012-9139-1.
V. M. Alamillo-López, V. Sánchez-Mendieta, O. F. Olea-Mejía, M. G. González-Pedroza, and R. A. Morales-Luckie, "Efficient removal of heavy metals from aqueous solutions using a bionanocomposite of eggshell/Ag-Fe," Catalysts, vol. 10, p. 727, 2020. doi: 10.3390/catal10070727.
A. El Badraoui, L. Nahali, Y. Miyah, F. Moumnani, O. Assila, H. Souhassou, et al., "High-efficiency of Peanut Shell Biosorbents in Cationic Dye Removal for Water Pollution Treatment," Moroccan Journal of Chemistry, vol. 12, pp. 12-1 (2024) 435-448, 2024.
S. Shoukat, H. N. Bhatti, M. Iqbal, and S. Noreen, "Mango stone biocomposite preparation and application for crystal violet adsorption: a mechanistic study," Microporous and Mesoporous Materials, vol. 239, pp. 180-189, 2017.