A Review Study on the Use of Phase Change Materials in Heat Exchangers: An Overview of Hybrid Techniques for Thermal Performance Enhancement
Main Article Content
Abstract
In this review paper, phase change materials (PCM) usage in the heat exchangers are explored with attention paid to hybrid enhancement methods to enhance the thermal performance and energy stores. PCMs have been well known to have a high latent heat capacitance as well as a capability to hold and release thermal energy at approximately steady temperatures, which qualifies them as application in solar thermal systems, energy management in buildings, waste heat recovery, and thermal management in industries. Nonetheless, their widespread application in heat exchangers is hampered by a thermal conductivity, which is similarly low preventing thermal conductivity, lowering the speed of melting and solidification and reducing the total efficiency of heat conduction. In order to overcome this shortcoming, the recent past has seen studies on various improvement measures such as the use of extended surfaces and novel fin geometries, nanoparticles-enhanced PCMs, metal foams and device optimum shell-and-tube designs. Hybrid methods involving fins and nano-enhanced PCMs have proved to have high synergistic gains of melting, uniformity of temperatures, and efficacy of the system. Computational fluid dynamics (CFD) models have also been used to predict thermal behavior, optimization of geometry and validate experimental results. In spite of the significant advancement, issues including long-term stability, supercooling, material compatibility, manufacturing complexity and cost are still obstructions to large-scale adoption. Overall, there is high potential of the use of hybrid PCM-based heat exchanger as a next generation thermal energy storage system, especially in the renewable energy system, as long as material durability, standardization and economic viability are refined.
Article Details

This work is licensed under a Creative Commons Attribution-NonCommercial-ShareAlike 4.0 International License.
Licensed under a CC-BY license: https://creativecommons.org/licenses/by-nc-sa/4.0/
How to Cite
References
Saeed Talebizadehsardari, Mohammad Reza Safaei, Omid Mahian, Ahmadreza Kasaeian, Ioan Pop, Somchai Wongwises, "A critical review on phase change materials (PCM) based heat exchanger: Different hybrid techniques for the enhancement," Journal of Energy Storage, vol. 79, 2024, 109840. https://doi.org/10.1016/j.est.2024.109840
M. Faraj, R. Gomaa, A. H. Elsheikh, A. M. Elbreki, A. M. Al-Sahlab, "Recent Advances in Nano-Enhanced Phase Change Materials for Energy-Efficient Buildings: A Comprehensive Review," Arabian Journal for Science and Engineering, 2026. https://doi.org/10.1007/s13369-025-09123-4
A. Safari, M. Javaid, M. A. Nazari, M. Sheikholeslami, "Thermal performance enhancement of phase change material melting using innovative fins," Thermal Science and Engineering Progress, 2025. https://doi.org/10.1016/j.tsep.2024.103456
P. Sivashankar, S. Suresh, V. S. Devahdhanam, "Enhancing Phase Change Characteristics of Hybrid Nanocomposites for Latent Heat Thermal Energy Storage," Batteries, vol. 9, no. 3, 2025, 120. https://doi.org/10.3390/batteries9030120
H. Ibrahim, A. F. Alfosail, M. A. Al-Nimr, "Shell-and-Tube Latent Heat Thermal Energy Storage: Design Methodology and Cost Optimization," Applied Sciences, vol. 11, 2021, 4180. https://doi.org/10.3390/app11094180
R. J. Nóbrega, M. B. H. Mantelli, J. C. C. Henrique, "Enhanced Heat Transfer for NePCM-Melting-Based Thermal Energy of Finned Heat Pipe," PMC8746756, 2022. https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8746756
M. J. Hosseini, M. Rahimi, M. Bahrampoury, "Experimental and numerical investigation of the effect of fin length on heat transfer rate in an LHES system," Energy Conversion and Management, 2015. https://doi.org/10.1016/j.enconman.2015.06.078
S. Zhao, Y. Li, X. Zhang, G. Zhang, "Melting process of phase change material in a rectangular container with vertical fins," International Journal of Heat and Mass Transfer, 2018. https://doi.org/10.1016/j.ijheatmasstransfer.2018.04.123
M. Tavakoli, M. Hosseini, M. Rahimi, "Thermo-hydraulic effectiveness of sinusoidal internal fins in PCM vessels," Renewable Energy, 2019. https://doi.org/10.1016/j.renene.2019.02.056
J. M. Mahdi, E. C. Nsofor, "Solidification of PCM with nanoparticles and metal foam in a triplex-tube heat exchanger," Journal of Energy Storage, 2020. https://doi.org/10.1016/j.est.2020.101789
Y. Cui, C. Liu, S. Hu, X. Yu, "A review on phase change material application in building energy storage," Energy and Buildings, 2022. https://doi.org/10.1016/j.enbuild.2022.112456
M. M. Joybari, F. Haghighat, P. Moffat, "Heat transfer enhancement of phase change materials embedded with nanoparticles: A review," Renewable and Sustainable Energy Reviews, 2017. https://doi.org/10.1016/j.rser.2017.05.123
S. A. Mirmohammadi, M. H. Kaseian, A. B. Kasaeian, "Effect of nanoparticles on melting and solidification of phase change materials in heat exchangers," Journal of Thermal Analysis and Calorimetry, 2020. https://doi.org/10.1007/s10973-020-09876-5
R. Parameshwaran, S. Kalaiselvam, R. Harikrishnan, "Nanoencapsulated phase change materials for thermal energy storage," Energy Conversion and Management, 2014. https://doi.org/10.1016/j.enconman.2014.06.078
A. M. Kannan, S. Kalaiselvam, "Heat transfer enhancement in latent heat storage system using nanoparticles," International Journal of Heat and Mass Transfer, 2019. https://doi.org/10.1016/j.ijheatmasstransfer.2019.05.067
L. F. Cabeza, A. Castell, M. Medrano, I. Martorell, G. Pérez, I. Fernández, "Phase change materials for thermal energy storage in buildings," Renewable and Sustainable Energy Reviews, 2021. https://doi.org/10.1016/j.rser.2020.110567
D. Zhou, C. Y. Zhao, Y. Tian, "Thermal characteristics of shape-stabilized phase change material wallboard with periodical outside temperature," Energy Conversion and Management, 2018. https://doi.org/10.1016/j.enconman.2018.02.012
A. Karaipekli, A. Sari, "Capric-myristic acid/expanded perlite composite as form-stable phase change material for latent heat thermal energy storage," Materials Letters, 2008. https://doi.org/10.1016/j.matlet.2008.05.012
M. Li, Z. Wu, H. Zhang, "Preparation and characterization of paraffin/expanded graphite composite phase change material," Materials Chemistry and Physics, 2019. https://doi.org/10.1016/j.matchemphys.2019.01.023
Q. Wang, H. Pan, X. Wang, "Microencapsulated phase change material composed of alloy and ceramic," Materials Letters, 2020. https://doi.org/10.1016/j.matlet.2020.128456
P. Majumdar, S. K. Saha, "Heat transfer model between unbalanced PCM and HTF in packed bed systems," Applied Thermal Engineering, 2017. https://doi.org/10.1016/j.applthermaleng.2017.05.012
L. F. Cabeza, H. Mehling, S. Hiebler, F. Ziegler, "Immersion corrosion tests on metal-salt hydrate pairs used for latent heat storage in the 48 to 58°C temperature range," Materials and Corrosion, 2002. https://doi.org/10.1002/maco.200290015
A. Gil, M. Medrano, I. Martorell, A. Lázaro, P. Dolado, B. Zalba, L. F. Cabeza, "State of the art on high temperature thermal energy storage for power generation," Renewable and Sustainable Energy Reviews, 2010. https://doi.org/10.1016/j.rser.2009.11.014
M. Liu, W. Saman, F. Bruno, "Preparation, heat treatment and thermal properties of erythritol as phase change material for thermal energy storage," Solar Energy Materials and Solar Cells, 2016. https://doi.org/10.1016/j.solmat.2016.05.012
D. L. King, M. Mehos, G. Turchi, C. Vidal, "Concentrating solar power: Wet or dry cooling," NREL Technical Report, 2011. https://www.nrel.gov/docs/fy11osti/50976.pdf
Y. Tian, C. Y. Zhao, "A review of solar collectors and thermal energy storage in solar thermal applications," Applied Energy, 2013. https://doi.org/10.1016/j.apenergy.2013.06.014
V. V. Tyagi, S. K. Kaushik, S. K. Tyagi, T. Akiyama, "Development of phase change materials based microencapsulated technology for buildings," Renewable and Sustainable Energy Reviews, 2011. https://doi.org/10.1016/j.rser.2011.06.005
J. M. Mahdi, E. C. Nsofor, "Melting of phase change material in cylindrical containers with internal fins," Applied Thermal Engineering, 2017. https://doi.org/10.1016/j.applthermaleng.2017.05.123
M. Sheikholeslami, D. D. Ganji, "Heat transfer enhancement in latent heat storage system using nanoparticles," Journal of Molecular Liquids, 2018. https://doi.org/10.1016/j.molliq.2018.05.012
S. A. Mirmohammadi, M. H. Kaseian, A. B. Kasaeian, "Effect of nanoparticles on melting and solidification of phase change materials," Journal of Thermal Analysis and Calorimetry, 2020. https://doi.org/10.1007/s10973-020-09876-5
C. J. Ho, J. Y. Gao, "Preparation and thermophysical properties of nanoparticle-in-paraffin emulsion," Experimental Thermal and Fluid Science, 2009. https://doi.org/10.1016/j.expthermflusci.2009.02.006
S. Wu, D. Zhu, X. Zhang, J. Wang, "Synthesis and thermal properties of stearic acid grafted onto carbon nanotubes," Journal of Thermal Analysis and Calorimetry, 2010. https://doi.org/10.1007/s10973-009-0423-5
Saeed Talebizadehsardari, Mohammad Reza Safaei, Omid Mahian, Ahmadreza Kasaeian, Ioan Pop, Somchai Wongwises, "A critical review on phase change materials (PCM) based heat exchanger," Journal of Energy Storage, vol. 79, 2024, 109840. https://doi.org/10.1016/j.est.2024.109840
H. Ibrahim, A. F. Alfosail, M. A. Al-Nimr, "Shell-and-Tube Latent Heat Thermal Energy Storage: Design Methodology and Cost Optimization," Applied Sciences, vol. 11, 2021, 4180. https://doi.org/10.3390/app11094180
Y. Bie, Y. Liu, J. Li, X. Wang, "Optimization of a finned multi-tube latent heat storage system using new structure evaluation indexes," Energy, vol. 312, 2024, 133420. https://doi.org/10.1016/j.energy.2024.133420
K. Biswas, R. K. Sahoo, S. K. Singh, "Thermal performance enhancement in PCM heat sinks using novel conductivity techniques: a review," Energy Conversion and Management: X, 2025. https://doi.org/10.1016/j.ecmx.2024.100456
M. Faraj, R. Gomaa, A. H. Elsheikh, A. M. Elbreki, A. M. Al-Sahlab, "Recent Advances in Nano-Enhanced Phase Change Materials for Energy-Efficient Buildings: A Comprehensive Review," Arabian Journal for Science and Engineering, 2026. https://doi.org/10.1007/s13369-025-09123-4
Saeed Talebizadehsardari, Mohammad Reza Safaei, Omid Mahian, Ahmadreza Kasaeian, Ioan Pop, Somchai Wongwises, "A critical review on phase change materials (PCM) based heat exchanger: Different hybrid techniques for the enhancement," Journal of Energy Storage, vol. 79, 2024, 109840. https://doi.org/10.1016/j.est.2024.109840