A Hybrid Activated Sludge-Moving Bed Biofilm Reactor System for the Treatment of Petroleum Refinery Effluents

Main Article Content

Nuha Muhsen Ali
Eynas Muhamad Majeed

Abstract

 A novel hybrid biological treatment system was developed to enhance the efficacy of effluent from petroleum refineries, as demonstrated in this experimental study. In the proposed pilot system, activated sludge is mixed with a sand filtering unit and a moving bed biofilm reactor (MBBR). There was a mix of attached and suspended microbes in the hybrid reactor, which consisted of an aeration tank containing activated sludge and polyurethane biofilm carriers. Shahid Tondgooyan Oil Refining Company's dissolved air flotation (DAF) discharged water was used to collect the influent wastewater. Researchers looked into how treatment efficacy was correlated with carrier mixing intensity and hydraulic retention time (HRT). Quantities of total dissolved solids (TDS), dissolved oxygen (DO), pH, total suspended solids (TSS), turbidity (TU), chemical oxygen demand (COD), biochemical oxygen demand (BOD5), and ammonia (NH3) were among the water quality metrics examined.
The results demonstrated that expanding the HRT length to 6 to 9 hours and increasing the carrier mixing intensity to a moderate range improved the system's carrier mixing intensity. The COD, NH 3, TSS, BOD 5, TU, and TDS removal efficiencies were approximately 98.6, 97.1, 82.4, 99.2, 98.7, 15.1 and 99.4 percent, respectively, when working circumstances were good. In contrast, increasing the mixing intensity to even higher levels reduced treatment efficiency slightly, probably due to biofilm dissociation and decreased microbial stability. Following a 9-hour HRT and a medium carrier mixing regime, the optimal operating conditions were identified. The major reason for this was the inclusion of the sand filtering unit, which greatly improved the effectiveness of turbidity removal. It appears that the hybrid system of sludge-MBBR-sand filter might be utilized to treat effluent from petroleum refineries, as it outperformed conventional biological treatment methods in eliminating a variety of contaminants.

Article Details

How to Cite
[1]
Nuha Muhsen Ali and E. M. Majeed, “A Hybrid Activated Sludge-Moving Bed Biofilm Reactor System for the Treatment of Petroleum Refinery Effluents”, Rafidain J. Eng. Sci., vol. 4, no. 1, pp. 555–565, Mar. 2026, doi: 10.61268/q89c8h46.
Section
Chemical Engineering

How to Cite

[1]
Nuha Muhsen Ali and E. M. Majeed, “A Hybrid Activated Sludge-Moving Bed Biofilm Reactor System for the Treatment of Petroleum Refinery Effluents”, Rafidain J. Eng. Sci., vol. 4, no. 1, pp. 555–565, Mar. 2026, doi: 10.61268/q89c8h46.

References

V. G. Khondabia, A. Fazlalia, and M. Arjomandzadeganb, “Biological treatment of phenol from petroleum refinery wastewater using mixed indigenous cultures in a rotating biological contactor: Experimental and statistical studies,” Desalination and Water Treatment, pp. 1–9, 2019.

I. Ratman et al., “Petroleum refinery wastewater treatment using three steps modified nanohybrid membrane coupled with ozonation as integrated pre-treatment,” Journal of Environmental Chemical Engineering, vol. 8, no. 4, p. 103978, 2020. DOI: https://doi.org/10.1016/j.jece.2020.103978

Y. Sun et al., “Physical pretreatment of petroleum refinery wastewater instead of chemicals addition for collaborative removal of oil and suspended solids,” Journal of Cleaner Production, vol. 278, p. 123821, 2021. DOI: https://doi.org/10.1016/j.jclepro.2020.123821

X. Tang, P. E. Eke, M. Scholz, and S. Huang, “Processes impacting on benzene removal in vertical-flow constructed wetlands,” Bioresource Technology, vol. 100, no. 1, pp. 227–234, 2009. DOI:https://doi.org/10.1016/j.biortech.2008.06.030

P. Compton et al., “Heterogeneous Fenton-Like Catalysis of Electrogenerated H₂O₂ for Dissolved RDX Removal,” Frontiers in Chemical Engineering, 2022.

P. Compton, N. Dehkordi, P. Larese-Casanova, and A. Alshawabkeh, “Activated carbon modifications for heterogeneous Fenton-like catalysis,” J. Chem. Eng. Catal., vol. 1, pp. 1–19, 2022.

N. R. Dehkordi et al., “Degradation of dissolved RDX, NQ, and DNAN by cathodic processes in an electrochemical flow-through reactor,” Journal of Environmental Chemical Engineering, vol. 10, no. 3, p. 107865, 2022. DOI: https://doi.org/10.1016/j.jece.2022.107865

M. Padaki et al., “Membrane technology enhancement in oil–water separation: A review,” Desalination, vol. 357, pp. 197–207, 2015. DOI: https://doi.org/10.1016/j.desal.2014.11.023

M. B. Fard et al., “Saline oily wastewater treatment using Lallemantia mucilage as a natural coagulant: Kinetic study, process optimization, and modeling,” Industrial Crops and Products, vol. 163, p. 113326, 2021. DOI: https://doi.org/10.1016/j.indcrop.2021.113326

S. Jafarinejad, “Recent developments in the application of sequencing batch reactor (SBR) technology for the petroleum industry wastewater treatment,” Chemistry International, vol. 3, no. 3, p. 241, 2017.

A. Zebardasti et al., “Analysis of patents in photocatalytic water and wastewater treatment. Part I–photocatalytic materials,” 2022. DOI: N/A

M. Seyyedi and B. Ayati, “Treatment of petroleum wastewater using a sequential hybrid system of electro-Fenton and NZVI slurry reactors,” International Journal of Environment and Waste Management, vol. 28, no. 3, pp. 328–348, 2021. DOI: https://doi.org/10.1504/IJEWM.2021.117051

M. Ebrahimi et al., “An optimized biological approach for treatment of petroleum refinery wastewater,” Journal of Environmental Chemical Engineering, vol. 4, no. 3, pp. 3401–3408, 2016. DOI: https://doi.org/10.1016/j.jece.2016.06.028

B. K. and N. S., US EPA Proceedings: Nanotechnology and the Environment, Arlington, VA, 2005.

S. Jafarinejad and S. C. Jiang, “Current technologies and future directions for treating petroleum refineries and petrochemical plants wastewaters,” Journal of Environmental Chemical Engineering, vol. 7, no. 5, p. 103326, 2019. DOI: https://doi.org/10.1016/j.jece.2019.103326

K. Tong et al., “Treatment of heavy oil wastewater by a conventional activated sludge process coupled with an immobilized biological filter,” International Biodeterioration & Biodegradation, vol. 84, pp. 65–71, 2013. DOI: https://doi.org/10.1016/j.ibiod.2012.05.013

K. V. Gernaey et al., “Activated sludge wastewater treatment plant modelling and simulation: State of the art,” Environmental Modelling & Software, vol. 19, no. 9, pp. 763–783, 2004. DOI: https://doi.org/10.1016/j.envsoft.2003.03.005

G. Najafpour et al., “Effect of organic loading on performance of rotating biological contactors using palm oil mill effluents,” Process Biochemistry, vol. 40, no. 8, pp. 2879–2884, 2005. DOI: https://doi.org/10.1016/j.procbio.2004.11.027

S. Singh, “Treatment and recycling of wastewater from oil refinery/petroleum industry,” Springer, pp. 303–332, 2019. DOI: https://doi.org/10.1007/978-981-13-1468-9_12

V. Ghalehkhondabi et al., “Performance analysis of four-stage rotating biological contactor in nitrification and COD removal from petroleum refinery wastewater,” Chemical Engineering and Processing, vol. 159, p. 108214, 2021. DOI: https://doi.org/10.1016/j.cep.2020.108214

[21] M. Hamoda, I. Al-Ghusain, and N. Al-Mutairi, “Sand filtration of wastewater for tertiary treatment and water reuse,” Desalination, vol. 164, no. 3, pp. 203–211, 2004. DOI: https://doi.org/10.1016/S0011-9164(04)00189-4

G. Ji, T. Sun, J. Ni, and J. Tong, “Anaerobic baffled reactor (ABR) for treating heavy oil produced water with high concentrations of salt and poor nutrient,” Bioresource Technology, vol. 100, no. 3, pp. 1108–1114, 2009. DOI: https://doi.org/10.1016/j.biortech.2008.08.024

H. A. Mokhtari, S. A. Mirbagheri, and N. R. Dehkordi, “Performance, evaluation, and modeling of an integrated petroleum refinery wastewater treatment system using multilayer perceptron neural networks,” Desalination and Water Treatment, vol. 212, pp. 31–42, 2021. DOI: https://doi.org/10.5004/dwt.2021.26612

J. Gregory, Particles in Water: Properties and Processes. Boca Raton, FL, USA: CRC Press, 2005. DOI: https://doi.org/10.1201/9780203508451

A. Almojjly, D. Johnson, D. L. Oatley-Radcliffe, and N. Hilal, “Removal of oil from oil-water emulsion by hybrid coagulation/sand filter as pre-treatment,” Journal of Water Process Engineering, vol. 26, pp. 17–27, 2018. DOI: https://doi.org/10.1016/j.jwpe.2018.08.008

S. A. Mirbagheri, S. Malekmohamadi, and M. Ehteshami, “Designing activated carbon and zeolite amended biosand filters: Optimization using response surface methodology,” Desalination and Water Treatment, vol. 93, pp. 48–60, 2017. DOI: https://doi.org/10.5004/dwt.2017.21260

S. Shivaranjani and L. M. Thomas, “Performance study for treatment of institutional wastewater by activated sludge process,” International Journal of Civil Engineering and Technology, vol. 8, 2017.

American Public Health Association, American Water Works Association, and Water Pollution Control Federation, Standard Methods for the Examination of Water and Wastewater. Baltimore, MD, USA: Port City Press, 1989.

N. Daneshvar, A. Oladegaragoze, and N. Djafarzadeh, “Decolorization of basic dye solutions by electrocoagulation: An investigation of the effect of operational parameters,” Journal of Hazardous Materials, vol. 129, no. 1–3, pp. 116–122, 2006. DOI: https://doi.org/10.1016/j.jhazmat.2005.08.033

M. Ebrahimi, H. Kazemi, S. Mirbagheri, and T. D. Rockaway, “Integrated approach to treatment of high-strength organic wastewater by using anaerobic rotating biological contactor,” Journal of Environmental Engineering, vol. 144, no. 2, 2018. DOI: https://doi.org/10.1061/(ASCE)EE.1943-7870.0001322

S. Tabraiz, S. Haydar, and G. Hussain, “Evaluation of a cost-effective and energy-efficient disc material for rotating biological contactors (RBC),” Desalination and Water Treatment, vol. 57, no. 43, pp. 20439–20446, 2016. DOI: https://doi.org/10.1080/19443994.2015.1106045

L. Di Palma and N. Verdone, “The effect of disk rotational speed on oxygen transfer in rotating biological contactors,” Bioresource Technology, vol. 100, no. 3, pp. 1467–1470, 2009. DOI: https://doi.org/10.1016/j.biortech.2008.08.022

E. Yoong and P. Lant, “Biodegradation of high strength phenolic wastewater using SBR,” Water Science and Technology, vol. 43, no. 3, pp. 299–306, 2001. DOI: https://doi.org/10.2166/wst.2001.0157

H. Qachach et al., “Biological treatment of fuel wastewater generated from a thermal power plant by continuous and discontinuous aeration,” Desalination and Water Treatment, vol. 222, pp. 145–155, 2021. DOI: https://doi.org/10.5004/dwt.2021.27072

S. A. Parsons, D. W. Dixon, P. J. Jarvis, and E. Sharp, Treatment of Waters with Elevated Organic Content. American Water Works Association, 2007.

M. Del Borghi, E. Palazzi, F. Parisi, and G. Ferraiolo, “Influence of process variables on the modelling and design of a rotating biological surface,” Water Research, vol. 19, no. 5, pp. 573–580, 1985. DOI: https://doi.org/10.1016/0043-1354(85)90055-9

Y. Yang, K. Tsukahara, and S. Sawayama, “Performance and methanogenic community of rotating disk reactor packed with polyurethane during thermophilic anaerobic digestion,” Materials Science and Engineering C, vol. 27, no. 4, pp. 767–772, 2007. DOI: https://doi.org/10.1016/j.msec.2006.05.051

S. Hamedi, V. Babaeipour, and M. Rouhi, “Design, construction and optimization a flexible bench-scale rotating biological contactor (RBC),” Bioprocess and Biosystems Engineering, vol. 44, no. 6, pp. 1071–1080, 2021. DOI: https://doi.org/10.1007/s00449-021-02508-9

G. Najafpour, A. Zinatizadeh, and L. Lee, “Performance of a three-stage aerobic RBC reactor in food canning wastewater treatment,” Biochemical Engineering Journal, vol. 30, no. 3, pp. 297–302, 2006. DOI: https://doi.org/10.1016/j.bej.2006.05.007

M. Irfan et al., “Effect of operating parameters and energy expenditure on the biological performance of rotating biological contactor for wastewater treatment,” Energies, vol. 15, no. 10, p. 3523, 2022. DOI: https://doi.org/10.3390/en15103523

S. Waqas et al., “Recent progress in integrated fixed-film activated sludge process for wastewater treatment: A review,” Journal of Environmental Management, vol. 268, p. 110718, 2020. DOI: https://doi.org/10.1016/j.jenvman.2020.110718

Similar Articles

You may also start an advanced similarity search for this article.